Carvão ativado para remoção de mercúrio
Buy Mercury Removal Activated Carbon
It mainly works through the synergistic effect of three mechanisms: physical adsorption, chemical adsorption and catalytic oxidation. Its well-developed microporous structure (0.5-2nm) first captures gaseous mercury (Hg⁰) through van der Waals forces; the surface functional groups modified by sulfur/halogen (such as -SH, -Cl) will form strong chemical bonds with mercury (such as the Hg-S bond with an energy of 250 kJ/mol), or oxidize Hg⁰ into a more easily adsorbed form, Hg²⁺; at the same time, the metal (Ag/Cu) loaded on the activated carbon or the oxygen-containing groups on the surface can also catalyze the conversion of Hg⁰ into HgO.
Desafios do sector
Risk of Secondary Pollution
- Saturated activated carbon, as a hazardous waste (with mercury content possibly exceeding 1%), if not handled properly, can lead to the secondary release of mercury. During the regeneration process, mercury-containing exhaust gas may be produced.
Risk of Performance Degradation
- The components such as SO₂ and moisture in the flue gas compete with the surface sites of the activated carbon for adsorption, thereby reducing the mercury removal efficiency. The fly ash clogs the pores of the activated carbon, resulting in a reduction of more than 50% in the specific surface area.
Safety Risk
- Mercury vapor is prone to volatilize at the temperature of activated carbon regeneration (>300℃), posing a threat to the health of operators. The halogens (such as Br) in the modified activated carbon may generate toxic dioxin by-products.
Technical Risk
- High-sulfur flue gas (SO₂ > 1000 ppm) will cause rapid deactivation of sulfur-modified activated carbon, and the adsorption kinetics of Hg⁰ significantly slows down at low temperatures (< 120℃).
tipos relacionados de carvão ativado
- Valor de iodo: 600-1200
- Tamanho da malha: 1×4/4×8/8×16/8×30/12×40/20×40/20×50/30×60/40×70 (Mais tamanho a pedido)
- Densidade aparente: 400-700
- Valor de iodo: 500-1300
- Tamanho da malha:0.9-1mm/1.5-2mm/3-4mm/6mm/8mm(Mais tamanho a pedido)
- Densidade aparente: 450-600
- Valor de iodo: 500-1300
- Dimensão da malha: 150/200/300/350 (outras dimensões a pedido)
- Densidade aparente: 450 - 550
- Valor de iodo: 400-800
- Tamanho da malha: 100×100×100mm/100×100×50mm (densidade celular personalizada a pedido)
- Densidade aparente: 350-450
- Diâmetro do furo: 1,5-8 mm
- Valor de iodo: 700-1200 mg/g
- Área de superfície: 700-1200 m²/g
- Densidade aparente: 320-550 kg/m³
- Valor de iodo: 700-1200 mg/g
- Área de superfície: 700-1200 m²/g
- Densidade aparente: 320-550 kg/m³
- Valor de iodo: 700-1200 mg/g
- Área de superfície: 700-1200 m²/g
- Densidade aparente: 300-650 kg/m³
- Valor de iodo: 700-1200 mg/g
- Área de superfície: 700-1200 m²/g
- Densidade aparente: 320-550 kg/m³
- Método de ativação: Ativação por vapor/gás a altas temperaturas
- Estrutura de poros: Microporosa dominada, distribuição uniforme dos poros
- Perfil ambiental: Sem químicos, baixo teor de cinzas
- Aplicações principais: Adsorção em fase gasosa, purificação de água potável
- Método de ativação: Ativação química (por exemplo, H₃PO₄/ZnCl₂) a temperaturas moderadas
- Estrutura de poros: Mesoporoso-rico, maior área de superfície
- Eficiência do processo: Tempo de ativação mais curto, rendimento 30-50% mais elevado
- Pós-tratamento: É necessária uma lavagem com ácido para remover os resíduos
- Funcionalização: Carregado com agentes activos (por exemplo, I₂/Ag/KOH)
- Adsorção direcionada: Captura melhorada de poluentes específicos (por exemplo, Hg⁰/H₂S/gases ácidos)
- Personalização: Quimicamente optimizado para contaminantes alvo
- Aplicações principais: Tratamento de gases industriais, proteção CBRN
Porquê utilizar o nosso carvão ativado
Precisely Customized Mercury Removal Solution：
1. For coal-fired power plants: High-sulfur tolerant modified carbon (maintains 90% efficiency even when SO₂ concentration exceeds 2000 ppm).
2. For waste incineration: Bromine-sulfur dual-modified carbon, simultaneously treating Hg⁰ and dioxins.
3. For non-ferrous metal smelting: Ag-Ce loaded carbon, suitable for ultra-high mercury concentrations of 10 to 50 mg/m³
Environmental Compliance and Resource Recycling Yield Double Benefit:
1. The emissions are ensured to meet the strictest standards.
2. The accompanying condensation purification device can recover 99.9% of high-purity mercury.
Revolutionary Cost-saving apabilities:
1. The total cost for mercury treatment has been reduced by 60%.
2. The microwave-acid washing combined process enables activated carbon to be reused 8 to 10 times, reducing the annual carbon consumption by 70%.
Processo e tecnologia
1.Physical Adsorption Method
Visão geral da solução
The physical adsorption method is the basic form of mercury removal by activated carbon. It captures mercury (Hg⁰) solely through the pore structure and surface physical properties of the activated carbon, without the need for chemical modification.
Principais vantagens
- Environmentally friendly: No introduction of substances such as sulfur and halogens that may cause secondary pollution. No risk of by-products. Avoid the problem of dioxin generation from brominated carbon.
- Ease of operation: No need for activation pre-treatment. It can be put into use directly after opening the box. The system is simple. The spraying system only requires a storage tank and a fan. The fixed bed does not require any additional oxidation equipment.
- Reliable basic performance: It can complete a single adsorption process within 0.1 seconds and can simultaneously remove some organic pollutants.
- Technical flexibility: It can be used as a pre-treatment process. First, physical adsorption is employed to reduce the load, and then chemical adsorption is applied for deep purification.
2. Chemical Modified Activated Carbon Method
Visão geral da solução
The chemical modification of activated carbon method is a technical approach that enhances mercury removal efficiency by chemically treating the surface of activated carbon to endow it with the ability to specifically adsorb or catalytically transform mercury.
Principais vantagens
- Ultra-high mercury removal capacity: The mercury adsorption capacity of the modified activated carbon can reach 5-50 mg Hg/g (while the ordinary carbon has only 0.1-0.5 mg/g), and the removal rate of Hg⁰ is over 90%
- Multi-functional collaborative purification: Sulfur-modified activated carbon can adsorb over 90% of As/Se, while halogen-modified activated carbon can degrade dioxins (with removal rate > 80%)
- Economic and environmental protection features: The metal-loaded carbon can be recycled 5-8 times. The mercury purity recovered through thermal regeneration is > 99.9%. The mercury enrichment capacity of the modified carbon reduces the amount of waste carbon by 80%.
- Strong technological scalability: Selecting the appropriate modifier based on the characteristics of the flue gas, and dynamically adjusting the injection volume through online mercury monitoring. The MOFs/activated carbon composite material can increase the adsorption capacity to over 100 mg/g.
3. Composite Processing Method
Visão geral da solução
The composite process method involves combining activated carbon with other purification technologies to create a synergistic mercury removal system, thereby overcoming the limitations of a single technology.
Principais vantagens
- Efficiency doubled: The SCR + activated carbon process has increased the Hg⁰ removal rate from 40% in the case of SCR alone to 95%. The O₃ oxidation + activated carbon process achieves a removal rate of over 99% for difficult-to-treat Hg⁰.
- Cost Optimization: The combined electrostatic dust removal system can reduce the consumption of activated carbon by 50%, and by utilizing the existing denitrification/desulfurization equipment, the investment can be saved by more than 30%.
- Enhanced anti-interference: Pre-desulfurization (such as wet desulfurization) can eliminate the influence of SO₂ on activated carbon, and pre-dust removal (such as bag filters) can prevent fly ash from blocking the pores of the carbon.
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